Download e-book for kindle: Al-based Energetic Nano Materials: Design, Manufacturing, by Carole Rossi

By Carole Rossi

ISBN-10: 184821717X

ISBN-13: 9781848217171

Over the prior 20 years, the quick improvement of nanochemistry and nanotechnology has allowed the synthesis of assorted fabrics and oxides within the type of nanopowders making it attainable to supply new vigorous compositions and nanomaterials.

This ebook has a bottom-up constitution, from nanomaterials synthesis to the applying fields. ranging from aluminum nanoparticles synthesis for gas software, it proposes a close state-of-the artwork of the various tools of coaching of aluminum-based reactive nanomaterials. It describes the concepts built for his or her characterization and, whilst to be had, an outline of the elemental mechanisms liable for their ignition and combustion. This booklet additionally offers the chances and boundaries of other full of life nanomaterials and comparable buildings in addition to the research in their chemical and thermal homes. the entire is rounded off with a glance on the performances of reactive fabrics by way of warmth of response and reactivity typically characterised because the self-sustained combustion speed. The e-book finally ends up with an outline of present reactive nanomaterials purposes underlying the promising integration of aluminum-based reactive nanomaterial into micro electromechanical systems.

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Sample text

9. 9. Typical DSC curve of the aluminum oxidation in O2/Ar oxidizing environment The complex oxidation process leading to the formation of the alumina passivation layer is still not well understood but few chemical reactions and phenomenological mechanisms responsible for oxidation have been proposed in the literature to fit the experimental results. They will be presented in the following sections. 1. Initial stage of aluminum oxidation from first principles calculations The early stage of aluminum oxidation (n = 0) has attracted much interest because of its practical importance and also because it was considered as a model system to understand the fundaments of the oxidation of metallic surfaces.

Increase in the reactivity It is observed that the reactivity of aluminum nanoparticles is considerably enhanced compared to micrometer-sized samples. 14 illustrates the effect of aluminum size on the Al+O2 reaction [SUN 06] where thermal analysis scans are given for 105 nm average diameter sample, 86 nm and 6 µm at a heating rate of 3°C/min under 25/75 O2/Ar atmosphere. We clearly see that there is a large exotherm reaction peak present for the nanoparticles before reaching the Al melting peak at 660 °C.

In particular, the reactions between the supercritical fluid and Al nanoparticles need to be prevented. 3. Molecular self-assembly of nanoparticles Molecular self-assembly has been investigated recently by a few teams to control the fuel/oxidizer interfacial contact area and improve the homogeneity of the nanothermite mixture. Self-assembly means that the Al nanoparticles can arrange by themselves, or directed by external forces, in a controlled manner around the oxidizers or vice versa. It can be done in inorganic, aqueous or organic solutions.

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Al-based Energetic Nano Materials: Design, Manufacturing, Properties and Applications by Carole Rossi

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